Alessandria to Catanzaro trains might be a good value for money solution: travelling in Italy by train is often rather cheap and faster than taking a bus indeed Trains leave from Alessandria and arrive at Catanzaro every about 3 hours on average. If travelling with Trenitalia, you need to know the Alessandria to Catanzaro train schedule: the first train leaves at 09:24, while the last ride is at 22:59. A Alessandria to Catanzaro train cost about 79.45 €. But how long is the train ride from Alessandria to Catanzaro? Your journey takes about 15 hours on average.