Aosta to Pozzallo trains might be a good value for money solution: travelling in Italy by train is often rather cheap and faster than taking a bus indeed Trains leave from Aosta and arrive at Pozzallo every about 6 hours on average. If travelling with Trenitalia, you need to know the Aosta to Pozzallo train schedule: the first train leaves at 16:38, while the last ride is at 19:26. A Aosta to Pozzallo train cost about 147.85 €. But how long is the train ride from Aosta to Pozzallo? Your journey takes about 2 hours on average.