Arezzo to Catania trains might be a good value for money solution: travelling in Italy by train is often rather cheap and faster than taking a bus indeed Trains leave from Arezzo and arrive at Catania Acquicella every about 2 hours on average. If travelling with Trenitalia, you need to know the Arezzo to Catania train schedule: the first train leaves at 07:25, while the last ride is at 18:13. A Arezzo to Catania train cost about 105.3 €. But how long is the train ride from Arezzo to Catania? Your journey takes about 22 hours on average. Thanks to Trenitalia, offers, you can save on your trip from Arezzo to Catania and find low cost tickets starting from 20 €!