Arezzo to Catanzaro trains might be a good value for money solution: travelling in Italy by train is often rather cheap and faster than taking a bus indeed Trains leave from Arezzo and arrive at Catanzaro every about 2 hours on average. If travelling with Trenitalia, you need to know the Arezzo to Catanzaro train schedule: the first train leaves at 04:25, while the last ride is at 20:14. A Arezzo to Catanzaro train cost about 79.8 €. But how long is the train ride from Arezzo to Catanzaro? Your journey takes about 10 hours on average. Thanks to Trenitalia, offers, you can save on your trip from Arezzo to Catanzaro and find low cost tickets starting from 25 €!