Arezzo to Catanzaro trains might be a good value for money solution: travelling in Italy by train is often rather cheap and faster than taking a bus indeed Trains leave from Arezzo and arrive at Catanzaro every about 2 hours on average. If travelling with Trenitalia, you need to know the Arezzo to Catanzaro train schedule: the first train leaves at 04:25, while the last ride is at 20:14. A Arezzo to Catanzaro train cost about 79.8 €. But how long is the train ride from Arezzo to Catanzaro? Your journey takes about 10 hours on average.