Arezzo to Mazara del Vallo trains might be a good value for money solution: travelling in Italy by train is often rather cheap and faster than taking a bus indeed Trains leave from Arezzo and arrive at Mazara del Vallo every about 3 hours on average. If travelling with Trenitalia, you need to know the Arezzo to Mazara del Vallo train schedule: the first train leaves at 07:25, while the last ride is at 18:13. A Arezzo to Mazara del Vallo train cost about 120.25 €. But how long is the train ride from Arezzo to Mazara del Vallo? Your journey takes about 11 hours on average.