Arezzo to Rosolini trains might be a good value for money solution: travelling in Italy by train is often rather cheap and faster than taking a bus indeed Trains leave from Arezzo and arrive at Rosolini every about 2 hours on average. If travelling with Trenitalia, you need to know the Arezzo to Rosolini train schedule: the first train leaves at 07:25, while the last ride is at 22:53. A Arezzo to Rosolini train cost about 92.4 €. But how long is the train ride from Arezzo to Rosolini? Your journey takes about 21 hours on average.