Arezzo to Sciacca trains might be a good value for money solution; travelling in Italy by train is often rather cheap and faster than taking a bus indeed. You can count on 1 daily rides to get from Arezzo to Sciacca. Trains leave from Arezzo and arrive at Castelvetrano every about 12 hours on average. If travelling with Trenitalia, you need to know the Arezzo to Sciacca train schedule: the first train leaves at 19:02, while the last ride is at 19:02. A Arezzo to Sciacca train cost about 137.35 €. But how long is the train ride from Arezzo to Sciacca? Your journey takes about 18 hours on average.