Catania to Sciacca trains might be a good value for money solution: travelling in Italy by train is often rather cheap and faster than taking a bus indeed Trains leave from Catania Acquicella and arrive at Castelvetrano every about 4 hours on average. If travelling with Trenitalia, you need to know the Catania to Sciacca train schedule: the first train leaves at 08:04, while the last ride is at 13:35. A Catania to Sciacca train cost about 16.1 €. But how long is the train ride from Catania to Sciacca? Your journey takes about 9 hours on average.