Catania to Vercelli trains might be a good value for money solution: travelling in Italy by train is often rather cheap and faster than taking a bus indeed Trains leave from Catania Acquicella and arrive at Vercelli every about 12 hours on average. If travelling with Trenitalia, you need to know the Catania to Vercelli train schedule: the first train leaves at 12:49, while the last ride is at 12:49. A Catania to Vercelli train cost about 122.4 €. But how long is the train ride from Catania to Vercelli? Your journey takes about 23 hours on average.