Catania to Vicenza trains might be a good value for money solution: travelling in Italy by train is often rather cheap and faster than taking a bus indeed Trains leave from Catania Acquicella and arrive at Vicenza every about 6 hours on average. If travelling with Trenitalia, you need to know the Catania to Vicenza train schedule: the first train leaves at 08:04, while the last ride is at 12:50. A Catania to Vicenza train cost about 141.4 €. But how long is the train ride from Catania to Vicenza? Your journey takes about 7 hours on average.