Catanzaro to Alessandria trains might be a good value for money solution: travelling in Italy by train is often rather cheap and faster than taking a bus indeed Trains leave from Catanzaro and arrive at Alessandria every about 2 hours on average. If travelling with Trenitalia, you need to know the Catanzaro to Alessandria train schedule: the first train leaves at 06:38, while the last ride is at 14:53. A Catanzaro to Alessandria train cost about 100.5 €. But how long is the train ride from Catanzaro to Alessandria? Your journey takes about 14 hours on average. Thanks to Trenitalia, offers, you can save on your trip from Catanzaro to Alessandria and find low cost tickets starting from 150 €!