Cattolica to Castelvetrano trains might be a good value for money solution: travelling in Italy by train is often rather cheap and faster than taking a bus indeed Trains leave from Cattolica-S. Giovanni-Gabicce and arrive at Castelvetrano every about 2 hours on average. If travelling with Trenitalia, you need to know the Cattolica to Castelvetrano train schedule: the first train leaves at 07:40, while the last ride is at 21:37. A Cattolica to Castelvetrano train cost about 104.15 €. But how long is the train ride from Cattolica to Castelvetrano? Your journey takes about 11 hours on average.