Chiari to Syracuse trains might be a good value for money solution: travelling in Italy by train is often rather cheap and faster than taking a bus indeed Trains leave from Chiari and arrive at Siracusa every about 3 hours on average. If travelling with Trenitalia, you need to know the Chiari to Syracuse train schedule: the first train leaves at 07:13, while the last ride is at 22:14. A Chiari to Syracuse train cost about 84.5 €. But how long is the train ride from Chiari to Syracuse? Your journey takes about 18 hours on average.