Città di Castello to Pozzallo trains might be a good value for money solution: travelling in Italy by train is often rather cheap and faster than taking a bus indeed Trains leave from Arezzo and arrive at Pozzallo every about 6 hours on average. If travelling with Trenitalia, you need to know the Città di Castello to Pozzallo train schedule: the first train leaves at 19:02, while the last ride is at 20:26. A Città di Castello to Pozzallo train cost about 113.15 €. But how long is the train ride from Città di Castello to Pozzallo? Your journey takes about 19 hours on average.