Empoli to Alcamo trains might be a good value for money solution: travelling in Italy by train is often rather cheap and faster than taking a bus indeed Trains leave from Empoli and arrive at Alcamo Diramazione every about 1 hour on average. If travelling with Trenitalia, you need to know the Empoli to Alcamo train schedule: the first train leaves at 06:01, while the last ride is at 22:33. A Empoli to Alcamo train cost about 100.25 €. But how long is the train ride from Empoli to Alcamo? Your journey takes about 16 hours on average.