Empoli to Catania trains might be a good value for money solution: travelling in Italy by train is often rather cheap and faster than taking a bus indeed Trains leave from Empoli and arrive at Catania Acquicella every about 6 hours on average. If travelling with Trenitalia, you need to know the Empoli to Catania train schedule: the first train leaves at 06:01, while the last ride is at 09:21. A Empoli to Catania train cost about 112.15 €. But how long is the train ride from Empoli to Catania? Your journey takes about 12 hours on average. Thanks to Trenitalia, offers, you can save on your trip from Empoli to Catania and find low cost tickets starting from 31 €!