Florence to Catania trains might be a good value for money solution: travelling in Italy by train is often rather cheap and faster than taking a bus indeed Trains leave from Firenze S. M. Novella and arrive at Catania Centrale every about 4 hours on average. If travelling with Trenitalia, you need to know the Florence to Catania train schedule: the first train leaves at 10:19, while the last ride is at 20:38. A Florence to Catania train cost about 94.80 €. But how long is the train ride from Florence to Catania? Your journey takes about 12 hours on average. Thanks to Trenitalia, offers, you can save on your trip from Florence to Catania and find low cost tickets starting from 69 €! If you need to travel this week, prices start from 119.40€. When booking your train ticket a few weeks in advance though, you can find low cost trains from Florence to Catania with fares starting from 94.80€, saving up to 20%.