Livorno to Alcamo trains might be a good value for money solution: travelling in Italy by train is often rather cheap and faster than taking a bus indeed Trains leave from Livorno Centrale and arrive at Alcamo Diramazione every about 2 hours on average. If travelling with Trenitalia, you need to know the Livorno to Alcamo train schedule: the first train leaves at 06:03, while the last ride is at 20:03. A Livorno to Alcamo train cost about 105.3 €. But how long is the train ride from Livorno to Alcamo? Your journey takes about 15 hours on average.