Livorno to Barcellona Pozzo di Gotto trains might be a good value for money solution: travelling in Italy by train is often rather cheap and faster than taking a bus indeed Trains leave from Livorno Centrale and arrive at Barcellona-Castroreale every about 2 hours on average. If travelling with Trenitalia, you need to know the Livorno to Barcellona Pozzo di Gotto train schedule: the first train leaves at 00:18, while the last ride is at 19:29. A Livorno to Barcellona Pozzo di Gotto train cost about 69.0 €. But how long is the train ride from Livorno to Barcellona Pozzo di Gotto? Your journey takes about 13 hours on average. Trenitalia offers 1 direct trains between these two cities.