Livorno to Caltanissetta trains might be a good value for money solution: travelling in Italy by train is often rather cheap and faster than taking a bus indeed Trains leave from Livorno Centrale and arrive at Caltanissetta Centrale every about 4 hours on average. If travelling with Trenitalia, you need to know the Livorno to Caltanissetta train schedule: the first train leaves at 00:18, while the last ride is at 19:29. A Livorno to Caltanissetta train cost about 77.5 €. But how long is the train ride from Livorno to Caltanissetta? Your journey takes about 18 hours on average.