Livorno to Castelvetrano trains might be a good value for money solution: travelling in Italy by train is often rather cheap and faster than taking a bus indeed Trains leave from Livorno Centrale and arrive at Castelvetrano every about 3 hours on average. If travelling with Trenitalia, you need to know the Livorno to Castelvetrano train schedule: the first train leaves at 00:18, while the last ride is at 19:29. A Livorno to Castelvetrano train cost about 76.65 €. But how long is the train ride from Livorno to Castelvetrano? Your journey takes about 20 hours on average.