Livorno to Catanzaro trains might be a good value for money solution: travelling in Italy by train is often rather cheap and faster than taking a bus indeed Trains leave from Livorno Centrale and arrive at Catanzaro every about 2 hours on average. If travelling with Trenitalia, you need to know the Livorno to Catanzaro train schedule: the first train leaves at 00:18, while the last ride is at 14:11. A Livorno to Catanzaro train cost about 98.1 €. But how long is the train ride from Livorno to Catanzaro? Your journey takes about 10 hours on average. Thanks to Trenitalia, offers, you can save on your trip from Livorno to Catanzaro and find low cost tickets starting from 87 €!