Livorno to Milazzo trains might be a good value for money solution: travelling in Italy by train is often rather cheap and faster than taking a bus indeed Trains leave from Livorno Centrale and arrive at Milazzo every about 2 hours on average. If travelling with Trenitalia, you need to know the Livorno to Milazzo train schedule: the first train leaves at 00:18, while the last ride is at 19:29. A Livorno to Milazzo train cost about 79.0 €. But how long is the train ride from Livorno to Milazzo? Your journey takes about 13 hours on average. Trenitalia offers 1 direct trains between these two cities.