Livorno to Modica trains might be a good value for money solution: travelling in Italy by train is often rather cheap and faster than taking a bus indeed Trains leave from Livorno Centrale and arrive at Modica every about 2 hours on average. If travelling with Trenitalia, you need to know the Livorno to Modica train schedule: the first train leaves at 16:03, while the last ride is at 22:09. A Livorno to Modica train cost about 103.55 €. But how long is the train ride from Livorno to Modica? Your journey takes about 20 hours on average.