Livorno to Palermo trains might be a good value for money solution: travelling in Italy by train is often rather cheap and faster than taking a bus indeed Trains leave from Livorno Centrale and arrive at Palermo Notarbartolo every about 2 hours on average. If travelling with Trenitalia, you need to know the Livorno to Palermo train schedule: the first train leaves at 16:03, while the last ride is at 22:09. A Livorno to Palermo train cost about 100.9 €. But how long is the train ride from Livorno to Palermo? Your journey takes about 18 hours on average. Thanks to Trenitalia, offers, you can save on your trip from Livorno to Palermo and find low cost tickets starting from 22 €!