Livorno to Palermo trains might be a good value for money solution; travelling in Italy by train is often rather cheap and faster than taking a bus indeed. You can count on 6 daily rides to get from Livorno to Palermo. Trains leave from Livorno Centrale and arrive at Palermo Notarbartolo every about 2 hours on average. If travelling with Trenitalia, you need to know the Livorno to Palermo train schedule: the first train leaves at 16:03, while the last ride is at 22:09. A Livorno to Palermo train cost about 100.9 €. But how long is the train ride from Livorno to Palermo? Your journey takes about 18 hours on average.