Livorno to Rosolini trains might be a good value for money solution: travelling in Italy by train is often rather cheap and faster than taking a bus indeed Trains leave from Livorno Centrale and arrive at Rosolini every about 2 hours on average. If travelling with Trenitalia, you need to know the Livorno to Rosolini train schedule: the first train leaves at 00:18, while the last ride is at 19:29. A Livorno to Rosolini train cost about 108.15 €. But how long is the train ride from Livorno to Rosolini? Your journey takes about 17 hours on average.