Livorno to San Cataldo trains might be a good value for money solution: travelling in Italy by train is often rather cheap and faster than taking a bus indeed Trains leave from Livorno Centrale and arrive at S. Cataldo every about 4 hours on average. If travelling with Trenitalia, you need to know the Livorno to San Cataldo train schedule: the first train leaves at 07:46, while the last ride is at 19:29. A Livorno to San Cataldo train cost about 119.15 €. But how long is the train ride from Livorno to San Cataldo? Your journey takes about 14 hours on average.