Livorno to Syracuse trains might be a good value for money solution: travelling in Italy by train is often rather cheap and faster than taking a bus indeed Trains leave from Livorno Centrale and arrive at Siracusa every about 1 hour on average. If travelling with Trenitalia, you need to know the Livorno to Syracuse train schedule: the first train leaves at 06:03, while the last ride is at 22:09. A Livorno to Syracuse train cost about 96.55 €. But how long is the train ride from Livorno to Syracuse? Your journey takes about 16 hours on average. Thanks to Trenitalia, offers, you can save on your trip from Livorno to Syracuse and find low cost tickets starting from 22 €!