Livorno to Syracuse trains might be a good value for money solution; travelling in Italy by train is often rather cheap and faster than taking a bus indeed. You can count on 10 daily rides to get from Livorno to Syracuse. Trains leave from Livorno Centrale and arrive at Siracusa every about 1 hour on average. If travelling with Trenitalia, you need to know the Livorno to Syracuse train schedule: the first train leaves at 06:03, while the last ride is at 22:09. A Livorno to Syracuse train cost about 96.55 €. But how long is the train ride from Livorno to Syracuse? Your journey takes about 16 hours on average.