Livorno to Vercelli trains might be a good value for money solution: travelling in Italy by train is often rather cheap and faster than taking a bus indeed Trains leave from Livorno Centrale and arrive at Vercelli every 30 minutes on average. If travelling with Trenitalia, you need to know the Livorno to Vercelli train schedule: the first train leaves at 03:09, while the last ride is at 18:52. A Livorno to Vercelli train cost about 35.35 €. But how long is the train ride from Livorno to Vercelli? Your journey takes about 5 hours on average.