Livorno to Vicenza trains might be a good value for money solution: travelling in Italy by train is often rather cheap and faster than taking a bus indeed Trains leave from Livorno Centrale and arrive at Vicenza every 60 minutes on average. If travelling with Trenitalia, you need to know the Livorno to Vicenza train schedule: the first train leaves at 06:12, while the last ride is at 18:52. A Livorno to Vicenza train cost about 51.45 €. But how long is the train ride from Livorno to Vicenza? Your journey takes about 4 hours on average. Thanks to Trenitalia, offers, you can save on your trip from Livorno to Vicenza and find low cost tickets starting from 27 €!