Matera to Alessandria trains might be a good value for money solution: travelling in Italy by train is often rather cheap and faster than taking a bus indeed Trains leave from Altamura, Salerno and arrive at Alessandria, Torino Porta Susa every about 2 hours on average. If travelling with Trenitalia, you need to know the Matera to Alessandria train schedule: the first train leaves at 07:09, while the last ride is at 23:33. A Matera to Alessandria train cost about 102.85 €. But how long is the train ride from Matera to Alessandria? Your journey takes about 12 hours on average.