Matera to Syracuse trains might be a good value for money solution: travelling in Italy by train is often rather cheap and faster than taking a bus indeed Trains leave from Altamura and arrive at Siracusa every about 12 hours on average. If travelling with Trenitalia, you need to know the Matera to Syracuse train schedule: the first train leaves at 07:09, while the last ride is at 07:09. A Matera to Syracuse train cost about 61.4 €. But how long is the train ride from Matera to Syracuse? Your journey takes about 16 hours on average.