Milan to Pozzallo trains might be a good value for money solution: travelling in Italy by train is often rather cheap and faster than taking a bus indeed Trains leave from Milano Porta Venezia and arrive at Pozzallo every about 12 hours on average. If travelling with Trenitalia, you need to know the Milan to Pozzallo train schedule: the first train leaves at 19:39, while the last ride is at 19:39. A Milan to Pozzallo train cost about 82.15 €. But how long is the train ride from Milan to Pozzallo? Your journey takes about 23 hours on average.