Naples to Pozzallo trains might be a good value for money solution: travelling in Italy by train is often rather cheap and faster than taking a bus indeed Trains leave from Napoli Centrale and arrive at Pozzallo every about 12 hours on average. If travelling with Trenitalia, you need to know the Naples to Pozzallo train schedule: the first train leaves at 23:53, while the last ride is at 23:53. A Naples to Pozzallo train cost about 64.15 €. But how long is the train ride from Naples to Pozzallo? Your journey takes about 11 hours on average.