Palermo to Vicenza trains might be a good value for money solution: travelling in Italy by train is often rather cheap and faster than taking a bus indeed Trains leave from Palermo Notarbartolo and arrive at Vicenza every about 2 hours on average. If travelling with Trenitalia, you need to know the Palermo to Vicenza train schedule: the first train leaves at 09:10, while the last ride is at 20:44. A Palermo to Vicenza train cost about 107.55 €. But how long is the train ride from Palermo to Vicenza? Your journey takes about 20 hours on average. Thanks to Trenitalia, offers, you can save on your trip from Palermo to Vicenza and find low cost tickets starting from 54 €!