Piombino to Alcamo trains might be a good value for money solution: travelling in Italy by train is often rather cheap and faster than taking a bus indeed Trains leave from Piombino and arrive at Alcamo Diramazione every about 6 hours on average. If travelling with Trenitalia, you need to know the Piombino to Alcamo train schedule: the first train leaves at 17:35, while the last ride is at 18:56. A Piombino to Alcamo train cost about 100.75 €. But how long is the train ride from Piombino to Alcamo? Your journey takes about 10 hours on average.