Piombino to Alessandria trains might be a good value for money solution: travelling in Italy by train is often rather cheap and faster than taking a bus indeed Trains leave from Piombino and arrive at Alessandria every about 2 hours on average. If travelling with Trenitalia, you need to know the Piombino to Alessandria train schedule: the first train leaves at 06:43, while the last ride is at 16:19. A Piombino to Alessandria train cost about 36.2 €. But how long is the train ride from Piombino to Alessandria? Your journey takes about 6 hours on average.