Piombino to Caltanissetta trains might be a good value for money solution: travelling in Italy by train is often rather cheap and faster than taking a bus indeed Trains leave from Piombino and arrive at Caltanissetta Centrale every about 12 hours on average. If travelling with Trenitalia, you need to know the Piombino to Caltanissetta train schedule: the first train leaves at 18:56, while the last ride is at 18:56. A Piombino to Caltanissetta train cost about 167.6 €. But how long is the train ride from Piombino to Caltanissetta? Your journey takes about 17 hours on average.