Piombino to Catania trains might be a good value for money solution; travelling in Italy by train is often rather cheap and faster than taking a bus indeed. You can count on 1 daily rides to get from Piombino to Catania. Trains leave from Piombino and arrive at Catania Acquicella every about 12 hours on average. If travelling with Trenitalia, you need to know the Piombino to Catania train schedule: the first train leaves at 17:35, while the last ride is at 17:35. A Piombino to Catania train cost about 221.9 €. But how long is the train ride from Piombino to Catania? Your journey takes about 20 hours on average.