Piombino to Catanzaro trains might be a good value for money solution: travelling in Italy by train is often rather cheap and faster than taking a bus indeed Trains leave from Piombino and arrive at Catanzaro every about 6 hours on average. If travelling with Trenitalia, you need to know the Piombino to Catanzaro train schedule: the first train leaves at 09:26, while the last ride is at 18:56. A Piombino to Catanzaro train cost about 78.0 €. But how long is the train ride from Piombino to Catanzaro? Your journey takes about 13 hours on average.