Piombino to Marsala trains might be a good value for money solution: travelling in Italy by train is often rather cheap and faster than taking a bus indeed Trains leave from Piombino and arrive at Mozia-Birgi every about 6 hours on average. If travelling with Trenitalia, you need to know the Piombino to Marsala train schedule: the first train leaves at 17:35, while the last ride is at 18:56. A Piombino to Marsala train cost about 152.45 €. But how long is the train ride from Piombino to Marsala? Your journey takes about 22 hours on average.