Piombino to Palermo trains might be a good value for money solution: travelling in Italy by train is often rather cheap and faster than taking a bus indeed Trains leave from Piombino and arrive at Palermo Notarbartolo every about 2 hours on average. If travelling with Trenitalia, you need to know the Piombino to Palermo train schedule: the first train leaves at 17:37, while the last ride is at 18:56. A Piombino to Palermo train cost about 97.15 €. But how long is the train ride from Piombino to Palermo? Your journey takes about 15 hours on average.