Piombino to Rosolini trains might be a good value for money solution: travelling in Italy by train is often rather cheap and faster than taking a bus indeed Trains leave from Piombino and arrive at Rosolini every about 2 hours on average. If travelling with Trenitalia, you need to know the Piombino to Rosolini train schedule: the first train leaves at 06:46, while the last ride is at 18:56. A Piombino to Rosolini train cost about 96.6 €. But how long is the train ride from Piombino to Rosolini? Your journey takes about 17 hours on average.