Piombino to Sciacca trains might be a good value for money solution; travelling in Italy by train is often rather cheap and faster than taking a bus indeed. You can count on 3 daily rides to get from Piombino to Sciacca. Trains leave from Piombino and arrive at Castelvetrano every about 4 hours on average. If travelling with Trenitalia, you need to know the Piombino to Sciacca train schedule: the first train leaves at 17:35, while the last ride is at 18:56. A Piombino to Sciacca train cost about 142.45 €. But how long is the train ride from Piombino to Sciacca? Your journey takes about 20 hours on average.