Piombino to Syracuse trains might be a good value for money solution: travelling in Italy by train is often rather cheap and faster than taking a bus indeed Trains leave from Piombino and arrive at Siracusa every about 4 hours on average. If travelling with Trenitalia, you need to know the Piombino to Syracuse train schedule: the first train leaves at 06:43, while the last ride is at 18:56. A Piombino to Syracuse train cost about 83.3 €. But how long is the train ride from Piombino to Syracuse? Your journey takes about 15 hours on average.