Piombino to Trapani trains might be a good value for money solution: travelling in Italy by train is often rather cheap and faster than taking a bus indeed Trains leave from Piombino and arrive at Trapani every about 6 hours on average. If travelling with Trenitalia, you need to know the Piombino to Trapani train schedule: the first train leaves at 17:35, while the last ride is at 18:56. A Piombino to Trapani train cost about 143.4 €. But how long is the train ride from Piombino to Trapani? Your journey takes about 21 hours on average.