Piombino to Vicenza trains might be a good value for money solution: travelling in Italy by train is often rather cheap and faster than taking a bus indeed Trains leave from Piombino and arrive at Vicenza every about 1 hour on average. If travelling with Trenitalia, you need to know the Piombino to Vicenza train schedule: the first train leaves at 06:46, while the last ride is at 18:56. A Piombino to Vicenza train cost about 43.95 €. But how long is the train ride from Piombino to Vicenza? Your journey takes about 7 hours on average.