Pompei to Avola trains might be a good value for money solution: travelling in Italy by train is often rather cheap and faster than taking a bus indeed Trains leave from Pompei and arrive at Avola every about 12 hours on average. If travelling with Trenitalia, you need to know the Pompei to Avola train schedule: the first train leaves at 08:06, while the last ride is at 08:06. A Pompei to Avola train cost about 60.75 €. But how long is the train ride from Pompei to Avola? Your journey takes about 12 hours on average.