Pompei to Vicenza trains might be a good value for money solution: travelling in Italy by train is often rather cheap and faster than taking a bus indeed Trains leave from Pompei and arrive at Vicenza every 30 minutes on average. If travelling with Trenitalia, you need to know the Pompei to Vicenza train schedule: the first train leaves at 06:28, while the last ride is at 22:21. A Pompei to Vicenza train cost about 91.4 €. But how long is the train ride from Pompei to Vicenza? Your journey takes about 8 hours on average.