Pozzallo to Castelvetrano trains might be a good value for money solution: travelling in Italy by train is often rather cheap and faster than taking a bus indeed Trains leave from Pozzallo and arrive at Castelvetrano every about 3 hours on average. If travelling with Trenitalia, you need to know the Pozzallo to Castelvetrano train schedule: the first train leaves at 06:14, while the last ride is at 18:41. A Pozzallo to Castelvetrano train cost about 20.6 €. But how long is the train ride from Pozzallo to Castelvetrano? Your journey takes about 14 hours on average.